Every voltage here comes from the standard reduction table plus the Nernst equation at 25 °C — swap metals, dilute a half-cell, or try the same metal twice.
Every voltage here comes from the standard reduction table plus the Nernst equation at 25 °C — swap metals, dilute a half-cell, or try the same metal twice.
Sliding this swaps in a fresh solution. The Nernst equation shifts the half-cell by 59.2/n mV per tenfold change — watch the meter move.
Sliding this swaps in a fresh solution. The Nernst equation shifts the half-cell by 59.2/n mV per tenfold change — watch the meter move.
No ion path, no cell — pull it and the meter dies.
The cell has 1 Ω of internal resistance, so a load sags the terminal voltage — and the cell discharges by Faraday’s law at 60× speed: the anode dissolves, the cathode plates, and the voltage drifts toward equilibrium.
Zn|1.00 M ‖ Cu|1.00 M reads 1.104 V at open circuit — Zinc is the anode. Record it, or connect a load and run the cell down.